CHEMICAL-TRANSFORMATIONS ON THE SURFACE OF [60]FULLERENE - SYNTHESIS OF [60]FULLERENO[1',2' 4,5]OXAZOLIDIN-2-ONE/

Authors
BANKS MR CADOGAN JIG GOSNEY I HODGSON PKG LANGRIDGESMITH PRR MILLAR JRA TAYLOR AT
Citation
Mr. Banks et al., CHEMICAL-TRANSFORMATIONS ON THE SURFACE OF [60]FULLERENE - SYNTHESIS OF [60]FULLERENO[1',2' 4,5]OXAZOLIDIN-2-ONE/, Tetrahedron letters, 35(48), 1994, pp. 9067-9070
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
48
Year of publication
1994
Pages
9067 - 9070
Database
ISI
SICI code
0040-4039(1994)35:48<9067:COTSO[>2.0.ZU;2-Z
Abstract
Base-induced alpha-elimination from substituted O-4-nitrophenylsulfony lhydroxamic acids has been used as a mild source of nitrenes for captu re by [60]fullerene; rearrangment of the resulting [60]fullereno[1',2' :2,3]aziridine bearing a N-ethoxycarbonyl grouping under the influence of phenol/chlorotrimethylsilane results in the quantitative formation of the title compound which can be cleaved to yield 1-hydroxy-2-N-met hylamino[60]fullerene.