A FACILE SYNTHESIS OF ALPHA-PHOSPHONO ESTERS THROUGH METHOXYCARBONYLATION OF ALPHA-PHOSPHONO CARBANIONS

Authors
GEIRSSON JKF NJARDARSON JT
Citation
Jkf. Geirsson et Jt. Njardarson, A FACILE SYNTHESIS OF ALPHA-PHOSPHONO ESTERS THROUGH METHOXYCARBONYLATION OF ALPHA-PHOSPHONO CARBANIONS, Tetrahedron letters, 35(48), 1994, pp. 9071-9072
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
48
Year of publication
1994
Pages
9071 - 9072
Database
ISI
SICI code
0040-4039(1994)35:48<9071:AFSOAE>2.0.ZU;2-F
Abstract
This paper describes a concise and effective synthesis of methyl alpha -phosphonoaryl acetates, effected by reacting alpha-phosphono carbanio ns with methyl chloroformate. Yields are high, and the purification of the products is readily achieved with column chromatography.