SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL ONE-DIMENSIONAL POLYMERIC COMPLEX, [BU(4)(N)N][TLWS4]

Authors
LANG JP LIU J CHEN MQ LU JM BIAN GQ XIN XQ
Citation
Jp. Lang et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL ONE-DIMENSIONAL POLYMERIC COMPLEX, [BU(4)(N)N][TLWS4], Journal of the Chemical Society, Chemical Communications, (23), 1994, pp. 2665-2666
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
23
Year of publication
1994
Pages
2665 - 2666
Database
ISI
SICI code
0022-4936(1994):23<2665:SASCOA>2.0.ZU;2-7
Abstract
Reaction of [NH4](2)[WS4], TIBr and [Bu(4)(n)N]Br in the solid state p roduces the mixed-metal sulfur complex [Bu(4)(n)N] [TIWS4]; an X-ray a nalysis shows that its structure can be described as infinite chains o f incomplete double cubane-like [WTI3S7] units interconnected via face -sharing to form a zigzag arrangement.