NOVEL ASYMMETRIC RING-OPENING REACTIONS OF SYMMETRICAL N-ACYLAZIRIDINES WITH ARENETHIOLS CATALYZED BY CHIRAL DIALKYL TARTRATE-DIETHYLZINC COMPLEXES

Authors
HAYASHI M ONO K HOSHIMI H OGUNI N
Citation
M. Hayashi et al., NOVEL ASYMMETRIC RING-OPENING REACTIONS OF SYMMETRICAL N-ACYLAZIRIDINES WITH ARENETHIOLS CATALYZED BY CHIRAL DIALKYL TARTRATE-DIETHYLZINC COMPLEXES, Journal of the Chemical Society, Chemical Communications, (23), 1994, pp. 2699-2700
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
23
Year of publication
1994
Pages
2699 - 2700
Database
ISI
SICI code
0022-4936(1994):23<2699:NARROS>2.0.ZU;2-C
Abstract
The asymmetric ring-opening reaction of N-acylaziridines with arenethi ols proceeds in the. presence of chiral zinc complexes prepared from d iethylzinc and L-(+)-diisopropyl tartrate (dipt) to afford trans-2-thi o-(N-acylamino)cyclohexane in up to 88% enantiomeric excess (e.e.).