DIASTEREOSELECTIVE CARBOMETALATION OF GAMMA-HETEROSUBSTITUTED VINYL METALS

Authors
MAREK I LEFRANCOIS JM NORMANT JF
Citation
I. Marek et al., DIASTEREOSELECTIVE CARBOMETALATION OF GAMMA-HETEROSUBSTITUTED VINYL METALS, Bulletin de la Societe chimique de France, 131(8), 1994, pp. 910-918
Citations number
57
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
131
Issue
8
Year of publication
1994
Pages
910 - 918
Database
ISI
SICI code
0037-8968(1994)131:8<910:DCOGVM>2.0.ZU;2-R
Abstract
The allylzincation of various gamma-heterosubstituted vinyl metals pro ceeds diastereoselectively. This represents a new synthetic approach t o constructing two or three adjacent stereogenic centers in acyclic sy stems.