J. Mcintosh et al., EXCIMER-LASER USED AS A MATERIALS CHARACTERIZATION TOOL - SULFIDE INCLUSION PRINTING IN STEEL, Laser chemistry, 13(2), 1993, pp. 121-128
An application of the excimer laser in the area of material characteri
zation making use of its ablative ability to perform surface sulphur p
rinting is presented. It is shown that the differential ablative and s
urface melting capability of the excimer laser is useful in microetchi
ng sulphide inclusions in flat polished steel samples and rough fractu
re surfaces. An optimum laser fluence is found to be that which melts
the sulphide particles without significant melting of the steel matrix
or causing overlap of the characteristics halo formed by the out-flow
ing liquid from the sulphides. The geometric similarity of the sulphid
e inclusions is maintained and its spatial extent is amplified about 1
0 times. This brings sub-micron sulphide particles into optical resolu
tion range. The liquid wetting behavior of the sulphide liquid is vari
able with Mn/Fe ratio and determines the extent of the halo formation.