M. Sampoli et al., DEPOLARIZED INTERACTION-INDUCED LIGHT-SCATTERING PAIR SPECTRUM OF MERCURY-VAPOR UP TO T=1073-K, Europhysics letters, 28(7), 1994, pp. 483-488
Mecury vapour depolarized-light scattering spectra have been measured
at various densities and temperatures up to 1070 K for the first time.
Absolute-intensity calibration has been done. Comparisons of the zero
th and second spectral moments with theoretical calculations using var
ious available pair potentials and the dipole-induced-dipole approxima
tion for the pair polarizability anisotropy have been performed. The l
arge disagreement between experimental values and theoretical calculat
ions is attributed to the breakdown of the classical point dipole appr
oximation.