K. Rottger et al., LATTICE-CONSTANTS AND THERMAL-EXPANSION OF H2O AND D2O ICE IH BETWEEN10 AND 265 K, Acta crystallographica. Section B, Structural science, 50, 1994, pp. 644-648
The lattice constants of powdered H2O and D2O ice Ih were measured in
the temperature range 10-265 K with synchrotron radiation to a precisi
on of typically 0.003% in a and 0.007% in c. The c/a ratio remains alm
ost constant with temperature, thus the thermal expansion is virtually
isotropic. Below 73 K, one observes a negative thermal expansion for
both light and heavy ice Ih. The temperature dependency of the thermal
expansion at higher temperatures follows roughly that of the specific
heat. Thus, the Gruneisen function is negative at low temperatures an
d is slowly varying above 120 K; the isotopic differences of the Grune
isen function are smaller than previously assumed.