ELECTROCRYSTALLIZATION, CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF HEXAPERYLENE HEXAFLUOROPHOSPHATE, (C20H12)(6)CENTER-DOT(-)()PF6()

Authors
KUHS WF MATTERN G BRUTTING W
Citation
Wf. Kuhs et al., ELECTROCRYSTALLIZATION, CRYSTAL-STRUCTURE AND PHYSICAL-PROPERTIES OF HEXAPERYLENE HEXAFLUOROPHOSPHATE, (C20H12)(6)CENTER-DOT(-)()PF6(), Acta crystallographica. Section B, Structural science, 50, 1994, pp. 741-746
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section B, Structural science → ACNP
ISSN journal
01087681
Volume
50
Year of publication
1994
Part
6
Pages
741 - 746
Database
ISI
SICI code
0108-7681(1994)50:<741:ECAPOH>2.0.ZU;2-1
Abstract
Electrocrystallization and crystal structure are reported for the 6:1 salt of perylene (PE) and hexafluorophosphate. The three-dimensional c rystal structure contains PE dimers with very small intradimer and lar ge interdimer separation. Measurements of static magnetic susceptibili ty and d.c. electrical conductivity characterize (PE)(6)PF6 as an orga nic semiconductor with comparatively large activation energy and one C urie-like radical spin per formula unit.