IN-SITU SCANNING VIBRATING ELECTRODE TECHNIQUE FOR THE CHARACTERIZATION OF INTERFACE BETWEEN LITHIUM ELECTRODE AND ELECTROLYTES CONTAINING ADDITIVES

Authors
ISHIKAWA M YOSHITAKE S MORITA M MATSUDA Y
Citation
M. Ishikawa et al., IN-SITU SCANNING VIBRATING ELECTRODE TECHNIQUE FOR THE CHARACTERIZATION OF INTERFACE BETWEEN LITHIUM ELECTRODE AND ELECTROLYTES CONTAINING ADDITIVES, Journal of the Electrochemical Society, 141(12), 1994, pp. 120000159-120000161
Citations number
13
Categorie Soggetti
Electrochemistry
Journal title
Journal of the Electrochemical Society → ACNP
ISSN journal
00134651
Volume
141
Issue
12
Year of publication
1994
Pages
120000159 - 120000161
Database
ISI
SICI code
0013-4651(1994)141:12<120000159:ISVETF>2.0.ZU;2-7
Abstract
New inorganic additives, tin (II) iodide (Snl(2)) and aluminum iodide (All(3)), improved the charge/discharge cycling efficiency of lithium (Li) electrodes in propylene carbonate electrolyte containing lithium perchlorate as the electrolytic salt. The synergistic effect of All(3) with and methylfuran on the cycling efficiency is also reported. The electrochemical behavior of the Li electrode/organic electrolyte inter face was investigated by an in situ scanning vibrating electrode techn ique. The relationship between the Li rechargeability and the interfac ial behavior of the Li electrode in the organic electrolyte in the abs ence and the presence of the additives is discussed.