METALATION OF ALKYNES .7. SUBSTITUENT EFFECTS IN ACETOXYMERCURATION OF 1-ARYLPROPYNES

Authors
FLORIS B TASSONI E
Citation
B. Floris et E. Tassoni, METALATION OF ALKYNES .7. SUBSTITUENT EFFECTS IN ACETOXYMERCURATION OF 1-ARYLPROPYNES, Organometallics, 13(12), 1994, pp. 4746-4750
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
12
Year of publication
1994
Pages
4746 - 4750
Database
ISI
SICI code
0276-7333(1994)13:12<4746:MOA.SE>2.0.ZU;2-M
Abstract
1-Arylpropynes were added to mercuric acetate in acetic acid, with the regiochemistry depending on the substituent. Kinetics of acetoxymercu ration were investigated. Second-order rate constants are best related by the Hammett sigma.