SYNTHESIS AND STRUCTURE OF A NOVEL BIS(STIBOLE)

Authors
HSU DP WARNER BP FISHER RA DAVIS WM BUCHWALD SL
Citation
Dp. Hsu et al., SYNTHESIS AND STRUCTURE OF A NOVEL BIS(STIBOLE), Organometallics, 13(12), 1994, pp. 5160-5162
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
12
Year of publication
1994
Pages
5160 - 5162
Database
ISI
SICI code
0276-7333(1994)13:12<5160:SASOAN>2.0.ZU;2-X
Abstract
The novel benzobis(stibole) 2a, synthesized from bis(zirconacycle) 1, crystallizes to place all three ring substituents in a syn orientation . Complex 2a stacks in such a manner so that the central phenyl rings of two adjacent Sb2C10 ring systems are nearly perfectly eclipsed.