The room-temperature ductility of FeAl is significantly reduced by env
ironmental embrittlement caused by the water vapor present in air. Sin
ce Fe-rich FeAl can fail by either transgranular or intergranular frac
ture in both wet and dry environments, the relative effects of the env
ironment on grain boundaries versus the grain interior are not known a
nd warrant study. In this investigation, the effect of test environmen
t on the tensile properties of single crystals of Fe-40Al was studied
in order to eliminate the effects of grain boundaries. It was found th
at the single crystals exhibited significantly higher room-temperature
ductilities when tested in a moisture-free environment, although '001
' cleavage fracture initiation remained the same as for samples tested
in air. At the 40 at% Al level, the degree of environmental embrittle
ment in the single crystals was similar to that observed in fine-grain
ed binary polycrystals and B-doped polycrystals.