OXIDATION-STATE-DEPENDENT CONFORMATION IN CP-ASTERISK-MO(DMIT)(2)(CIRCLE-MINUS) AND ANTIFERROMAGNETIC ORDERING (T-N=8 K) OF THE NEUTRAL 17-ELECTRON COMPLEX CP-ASTERISK-MO(DMIT)(2)(CIRCLE-MINUS)

Authors
FOURMIGUE M COULON C
Citation
M. Fourmigue et C. Coulon, OXIDATION-STATE-DEPENDENT CONFORMATION IN CP-ASTERISK-MO(DMIT)(2)(CIRCLE-MINUS) AND ANTIFERROMAGNETIC ORDERING (T-N=8 K) OF THE NEUTRAL 17-ELECTRON COMPLEX CP-ASTERISK-MO(DMIT)(2)(CIRCLE-MINUS), Advanced materials, 6(12), 1994, pp. 948-952
Citations number
33
Categorie Soggetti
Material Science
Journal title
Advanced materials → ACNP
ISSN journal
09359648
Volume
6
Issue
12
Year of publication
1994
Pages
948 - 952
Database
ISI
SICI code
0935-9648(1994)6:12<948:OCIC>2.0.ZU;2-9
Abstract
Metal dithiolene complexes are attractive for the development of novel materials with extended electronic properties. The preparation of Cp Mo(dmit)(2)(-) and its investigation by cyclic voltammetry, antiferrom agnetic resonance, and electron paramagnetic resonance are described. Complexes of this class, i.e., with heteroatom substitution on the dmi t dithiolene ligand, are shown to exhibit conformational flexibility d irectly related to the orbital occupancy.