S. Chandrasekar et Mm. Chaudhri, THE EXPLOSIVE DISINTEGRATION OF PRINCE-RUPERT-DROPS, Philosophical magazine. B. Physics of condensed matter. Structural, electronic, optical and magnetic properties, 70(6), 1994, pp. 1195-1218
A high-speed photographic study has been made of the explosive disinte
gration of Prince Rupert's drops. The drops were prepared by quenching
molten soda-lime glass in water. The disintegration of a drop was ini
tiated by exploding a small (26 mg) lead azide charge or by impacting
with a hardened steel chisel on to the tail of the drop. The entire fr
agmentation process was recorded at framing rates ranging from 6500 fr
ames s-1 to 0.5 x 10(6) s-1. The high-speed photographic sequences rev
ealed that in a disintegrating drop the crack front, having been initi
ated in the tail, propagated at a high velocity (almost-equal-to 1450-
1900 ms-1) within the tensile zone, towards the drop's head. Finger-ty
pe bifurcating cracks at the crack front were observed. High-speed pho
tographic observations, combined with an analysis of the fragment size
s, indicated that the fast-moving cracks slowed down dramatically on e
ntering the surface compression zone. Sequences of high-speed shadowgr
aphs also revealed that the rapidly moving crack front did not produce
any strong stress waves in the drops which could have contributed to
their explosive disintegration. The main features of crack propagation
in a drop were found to be similar to those of the self-propagating c
racks in thermally tempered soda-lime glass blocks. Measurements of re
sidual stresses in the drops using an indentation technique showed tha
t the surface compressive stress was almost-equal-to 90-170 MPa and th
e tension zone extended across almost-equal-to 70% of the drop's diame
ter at the head. Both of these values are similar to those found for t
hermally tempered soda-lime glass blocks. A model based on the repeate
d bifurcation of fast-moving cracks within the tensile zone in the dro
p has been proposed to explain its explosive disintegration.