I. Endler et al., PREPARATION, CHARACTERIZATION AND WEAR BEHAVIOR OF TINX-COATED CERMETS OBTAINED BY PLASMA-ENHANCED CHEMICAL-VAPOR-DEPOSITION, Journal of Materials Science, 29(23), 1994, pp. 6097-6103
Commercial cermet inserts were coated with titanium nitride by plasma-
enhanced chemical vapour deposition (PECVD) using a pulsed direct curr
ent (d.c.) glow discharge. The influence of the coating parameters on
the deposition rate, on the layer composition, on the layer-substrate
interface, on the structure and on the microhardness of the layers was
investigated for deposition temperatures in the range 500-700 degrees
C. The adhesive strengths, and some mechanical properties, of the coa
ted cermets were characterized by scratch tests, by friction wear inve
stigations and by measurement of the transverse rupture strength. The
wear behaviour was examined in the cutting tests. It was found that Ti
Nx-coatings deposited with a sufficiently high deposition rate and pla
sma power density have a low oxygen and chlorine content and that they
are nearly stoichiometric. The layers usually have a columnar structu
re with a (200) texture. A granular, equiaxed structure was observed w
ithin a small range of deposition conditions. In interrupted and conti
nuous turning tests with steel and grey cast iron, a high cutting perf
ormance of the coated inserts, which depended on the coating thickness
and on the deposition temperature, was achieved.