Dm. Hoffman et al., PLASMA-ENHANCED CHEMICAL-VAPOR-DEPOSITION OF SILICON-NITRIDE FILMS FROM A METAL-ORGANIC PRECURSOR, Journal of materials research, 9(12), 1994, pp. 3019-3021
Silicon nitride films are grown by plasma enhanced chemical vapor depo
sition from tetrakis(dimethylamido)silicon, Si(NMe2)4, and ammonia pre
cursors at substrate temperatures of 200-400-degrees-C. Backscattering
spectrometry shows that the films are close to stoichiometric. Depth
profiling by Auger electron spectroscopy shows uniform composition and
no oxygen or carbon contamination in the bulk. The films are featurel
ess by scanning electron microscopy under 100,000 x magnification.