AN ALTERNATIVE INTERPRETATION OF CS2- RESONANT STATES

Citation
Av. Pogulay et al., AN ALTERNATIVE INTERPRETATION OF CS2- RESONANT STATES, Journal of electron spectroscopy and related phenomena, 70(2), 1994, pp. 95-101
Citations number
15
Categorie Soggetti
Spectroscopy
ISSN journal
03682048
Volume
70
Issue
2
Year of publication
1994
Pages
95 - 101
Database
ISI
SICI code
0368-2048(1994)70:2<95:AAIOCR>2.0.ZU;2-Q
Abstract
An alternative interpretation of resonant states in the molecular nega tive ions CS2-. is fulfilled with the help of the combined application of previously reported data on resonant dissociative electron attachm ent, photoelectron spectroscopy, electron energy loss spectroscopy and absorption spectroscopy. It is shown that CS2 at energies ranging fro m 3.35 to 7.80 eV is formed by the core-excited Feshbach resonance mec hanism of the inter-shell type involving singlet excitation of a molec ule and capture of an additional electron into the Rydberg orbital.