Various thin films of germanium silicate glass with high germania cont
ent have been fabricated by a sol-gel method. After densification, the
se films have a high optical quality and can be used as planar wavegui
des. The densification behavior of these films was studied by measurem
ents of the index of refraction, as a function of heat treatment tempe
ratures, using ellipsometry. The relationship of refractive index vers
us GeO2 content follows the additive Lorentz-Lorenz model. Waveguiding
Raman spectroscopy suggested the formation of Si-O-Ge linkages in the
se films without phase segregation. Various waveguide propagation char
acteristics, at 632.8 nm, were studied using a prism coupling techniqu
e. The propagation loss rate of a 50GeO(2)0-50SiO(2) glass waveguide w
as measured as 3.31 dB/cm.