HIGH-PRESSURE C-13 NMR OF C-60 IN THE SOLID-STATE

Citation
Jh. Walton et T. Gullion, HIGH-PRESSURE C-13 NMR OF C-60 IN THE SOLID-STATE, Journal of physical chemistry, 98(49), 1994, pp. 13064-13066
Citations number
26
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
98
Issue
49
Year of publication
1994
Pages
13064 - 13066
Database
ISI
SICI code
0022-3654(1994)98:49<13064:HCNOCI>2.0.ZU;2-9
Abstract
We report high-pressure C-13 NMR spin-lattice relaxation times for C-6 0 at 295 K. A discontinuity in T-1 is observed at 2.7 +/- 0.2 kbar and is attributed to the face-centered cubic to simple cubic structural p hase transition. The activation volume for molecular reorientation in the fee phase is 3.5 +/- cm(3)/mol.