FACILE COMPLEXATION OF 1,1'-BIS(DIPHENYLPHOSPHINO) RUTHENOCENE (DPPR)TO RUTHENIUM(II) - SIMPLE ENTRY TO STABLE BIMETALLIC RUTHENORUTHENOCENYL SYSTEM

Authors
WEI B LI SH LEE HK HOR TSA
Citation
B. Wei et al., FACILE COMPLEXATION OF 1,1'-BIS(DIPHENYLPHOSPHINO) RUTHENOCENE (DPPR)TO RUTHENIUM(II) - SIMPLE ENTRY TO STABLE BIMETALLIC RUTHENORUTHENOCENYL SYSTEM, Journal of organometallic chemistry, 527(1-2), 1997, pp. 133-136
Citations number
57
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
527
Issue
1-2
Year of publication
1997
Pages
133 - 136
Database
ISI
SICI code
0022-328X(1997)527:1-2<133:FCO1R(>2.0.ZU;2-N
Abstract
Phosphine exchange occurs rapidly between RuCl2(PPh(3))(n) (n = 3, 4) and Ru(C(5)H(4)PPh(2))(2) (dppr) at room temperature to give RuCl2(dpp r)(PPh(3)), 1. Triphenylphosphine is more substitutionally labile than dppr in 1; selective phosphine substitution of 1 with CO and CH3CN gi ves [RuCl2(CO)(dppr)] and two geometric isomers of [RuCl2(NCCH3)(2)(dp pr)] respectively.