SYNTHESIS AND CHARACTERIZATION OF PLATINUM(0) COMPLEXES OF PROPENOATES - X-RAY-DIFFRACTION STUDY OF [PT(CH2=CHCO(2)CH(2)PH)(PPH(3))(2)]

Authors
CHALONER PA DAVIES SE HITCHCOCK PB
Citation
Pa. Chaloner et al., SYNTHESIS AND CHARACTERIZATION OF PLATINUM(0) COMPLEXES OF PROPENOATES - X-RAY-DIFFRACTION STUDY OF [PT(CH2=CHCO(2)CH(2)PH)(PPH(3))(2)], Journal of organometallic chemistry, 527(1-2), 1997, pp. 145-154
Citations number
48
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
527
Issue
1-2
Year of publication
1997
Pages
145 - 154
Database
ISI
SICI code
0022-328X(1997)527:1-2<145:SACOPC>2.0.ZU;2-S
Abstract
Reaction of [Pt(C2H4)(PPh(3))(2)] with propenoate or 2-methylpropenoat e esters gave the complexes [Pt(propenoate)(PPh(3))(2)] in good yield. These have been characterised by H-1, C-13, P-31 and Pt-195 NMR spect roscopy. The complex of benzyl propenoate has been characterised in a diffraction study. Reaction of the complexes produced with tricyclohex ylphosphine, PCy(3), gave [Pt(propenoate)(PCy(3))(PPh(3))]. The propen oate complexes were shown to be more stable than those of the 2-methyl propenoates.