2 STRUCTURALLY DIFFERENT STIBOCENIUM CATI ONS

Authors
SITZMANN H EHLEITER Y WOLMERSHAUSER G ECKER A UFFING C SCHNOCKEL H
Citation
H. Sitzmann et al., 2 STRUCTURALLY DIFFERENT STIBOCENIUM CATI ONS, Journal of organometallic chemistry, 527(1-2), 1997, pp. 209-213
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
527
Issue
1-2
Year of publication
1997
Pages
209 - 213
Database
ISI
SICI code
0022-328X(1997)527:1-2<209:2SDSCO>2.0.ZU;2-8
Abstract
After most recent results in alkali metal cyclopentadienide chemistry we succeeded in preparing two structurally different sandwich compound s of antimony: [Cp(2)'''Sb](+) AlCl4- 1 and [Cp(2)Sb](+) AlI4- 2 (Cp' '' = 1,2,4-tri(tert-butyl)cyclopentadienyl; Cp = pentamethylcyclopent adienyl). The cations of 1 and 2, which are isoelectronic with stannoc ene and similar to their lighter group homologue [Cp(2)As](+), are th e first structurally characterized representatives of the stibocenium- species.