FLASH VACUUM THERMOLYSIS OF 4 MEMBERED RING CONTAINING NITROGEN ATOM .3. THERMAL-DECOMPOSITION OF BETA-LACTAMS

Authors
BARTNIK R LESNIAK S
Citation
R. Bartnik et S. Lesniak, FLASH VACUUM THERMOLYSIS OF 4 MEMBERED RING CONTAINING NITROGEN ATOM .3. THERMAL-DECOMPOSITION OF BETA-LACTAMS, Polish Journal of Chemistry, 68(12), 1994, pp. 2605-2611
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
68
Issue
12
Year of publication
1994
Pages
2605 - 2611
Database
ISI
SICI code
0137-5083(1994)68:12<2605:FVTO4M>2.0.ZU;2-N
Abstract
The thermal decomposition of beta-lactams under FVT conditions was stu died. It has been found that the regiochemistry of the ring cleavage d epends on the nature of substituents. 1,4-Diradical stepwise mechanism of these reactions has been postulated.