COMPARISON OF THE REACTIVITY OF AMMONIUM HALIDES USING HYDROGEN-ISOTOPE EXCHANGE-REACTION IN A GAS-SOLID SYSTEM

Authors
IMAIZUMI H SHINBO H
Citation
H. Imaizumi et H. Shinbo, COMPARISON OF THE REACTIVITY OF AMMONIUM HALIDES USING HYDROGEN-ISOTOPE EXCHANGE-REACTION IN A GAS-SOLID SYSTEM, Journal of radioanalytical and nuclear chemistry, 188(5), 1994, pp. 331-339
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
188
Issue
5
Year of publication
1994
Pages
331 - 339
Database
ISI
SICI code
0236-5731(1994)188:5<331:COTROA>2.0.ZU;2-9
Abstract
In order to reveal the behavior of the hydrogen atoms in an ammonium s alt, the hydrogen-isotope exchange reaction between each of the three ammonium halides and tritiated water vapor was followed at 50 - 80-deg rees-C. Analyzing the data obtained by the A''-McKay plot method, the following has been quantitatively clarified: both the reactivity of an ammonium halide and the temperature dependence of its reactivity incr ease when the electronegativity of the halogen element in the ammonium halide is larger.