J. Henk et R. Feder, SPIN POLARIZATION IN NORMAL PHOTOEMISSION BY LINEARLY POLARIZED-LIGHTFROM NONMAGNETIC (110) SURFACES, Europhysics letters, 28(8), 1994, pp. 609-614
For linearly polarized radiation with a non-zero surface projection of
the electric-field vector, photoelectrons emitted normal to non-magne
tic surfaces with an at most twofold rotation axis generally have a sp
in polarization component perpendicular to the surface. This is firstl
y substantiated by symmetry arguments. For cubic (110) surfaces, an an
alytical calculation reveals that this effect is due to the spin-orbit
-induced hybridization of basis functions of different spatial-symmetr
y types. Numerical relativistic one-step-model multiple-scattering cal
culations for Pt(110) yield polarization values up to 60%, which depen
d sensitively on the surface reconstruction.