The present study describes the effect of electrode material on the pe
rformance of a screen-printed thick-film SnO2 gas sensor. The response
of the sensor, i.e., the percentage change in the sensor resistance u
pon exposure to H-2, CO and CH4, has been studied for two different el
ectrodes of silver and gold. It has been observed that the sensitivity
of the thick-film SnO2 sensor for H-2 and CO with silver (Ag) is much
higher (about 65.5% and 42.6%, respectively) as compared to the Au-el
ectrode sensor. A possible mechanism for the higher sensitivity of the
Ag-based SnO2 sensor has been suggested in terms of autodoping at the
time of firing of the SnO2 layer. The idea of autodoping has been con
firmed by performing Ag doping of SnO2 (with a Au electrode) and study
ing its performance.