Y. Morishige et S. Kishida, THICK GOLD-FILM DEPOSITION BY HIGH-REPETITION VISIBLE PULSED-LASER CHEMICAL-VAPOR-DEPOSITION, Applied physics. A, Solids and surfaces, 59(4), 1994, pp. 395-399
A highly conductive gold film, over 10 mum-thick with well-controlled
linewidth, has been successfully deposited from dimethyl-gold-acetylac
etonate and its fluorinated derivative by pyrolytic CVD (Chemical Vapo
r Deposition) with a high-repetition, visible, pulsed laser. The therm
al damage to the polyimide substrate has been substantially suppressed
by reducing the thermal diffusion length within 0.2 mum in pulsed-las
er-induced transient heating, in contrast to the cw laser-CVD scheme.
Reproducible and low contact resistance as low as 0.5 OMEGA between th
e written line and the existing gold line has been obtained. Sufficien
tly tough adhesion to polyimide has been observed for the deposit from
dimethyl-gold-acetylacetonate. Reasonable agreement has been obtained
between the observed deposition characteristics and analytical result
s for precursor supply rate and temperature increase during short-puls
e irradiation.