FRANCK-CONDON RULES FOR PROBABILITIES OF TRANSITIONS BETWEEN RYDBERG LEVELS OF ATOMIC-HYDROGEN IN A MAGNETIC-FIELD

Citation
Pa. Braun et D. Delande, FRANCK-CONDON RULES FOR PROBABILITIES OF TRANSITIONS BETWEEN RYDBERG LEVELS OF ATOMIC-HYDROGEN IN A MAGNETIC-FIELD, Journal of physics. B, Atomic molecular and optical physics, 27(23), 1994, pp. 5621-5636
Citations number
28
Categorie Soggetti
Physics, Atomic, Molecular & Chemical",Optics
ISSN journal
09534075
Volume
27
Issue
23
Year of publication
1994
Pages
5621 - 5636
Database
ISI
SICI code
0953-4075(1994)27:23<5621:FRFPOT>2.0.ZU;2-U
Abstract
Transitions between highly excited quadratic Zeeman levels of atomic h ydrogen are considered. If the lower state is l-mixed, simple semiclas sical rules are shown to exist determining transitions with the larges t probabilities. These rules link the turning angles of oscillation of the Runge-Lenz vector of the atomic electron and (in the case of the irregular upper states) the direction of the periodic orbits of the el ectron at the moment when it passes through the nucleus. The Fourier t ransform of intensities of the Rydberg-Rydberg transitions in the magn etic field is investigated.