K. Tharanikkarasu et G. Radhakrishnan, A NOVEL POLYURETHANE MACROINITIATOR FOR FREE-RADICAL POLYMERIZATION, European Polymer Journal, 30(12), 1994, pp. 1351-1355
Polyurethane macroinitiator (PUMI) has been prepared from toluene diis
ocyanate and benzopinacol and successfully used to polymerize acryloni
trile (AN). The effects of PUMI and AN concentrations and polymerizati
on time on the yield, number average molecular weight and intrinsic vi
scosity of the resulting Polyacrylonitrile have been studied.