REGIOSELECTIVE SYNTHESIS OF CERALURE-B-1 AND CERALURE-A, ETHYL CIS-5-IODO-TRANS-2-METHYLCYCLOHEXANE-1-CARBOXYLATE AND ANS-5-IODO-TRANS-2-METHYLCYCLOHEXANE-1-CARBOXYLATE

Citation
Jw. Avery et al., REGIOSELECTIVE SYNTHESIS OF CERALURE-B-1 AND CERALURE-A, ETHYL CIS-5-IODO-TRANS-2-METHYLCYCLOHEXANE-1-CARBOXYLATE AND ANS-5-IODO-TRANS-2-METHYLCYCLOHEXANE-1-CARBOXYLATE, Tetrahedron letters, 35(50), 1994, pp. 9337-9338
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
50
Year of publication
1994
Pages
9337 - 9338
Database
ISI
SICI code
0040-4039(1994)35:50<9337:RSOCAC>2.0.ZU;2-V
Abstract
Reaction of trans-2-methyl-6-oxabicyclo[3.2.1]octan-7-one with trimeth ylsilyl iodide, generated in situ, followed by refluxing with ethanol gives regioselectively ethyl cis-(and trans-) 5-iodo-2-methylcyclohexa ne-1-carboxylate, a persistent attractant for male Mediterranean fruit flies.