SYNTHESIS OF BETA,GAMMA-UNSATURATED AMINO-ACID DERIVATIVES BY ALKYNE CARBOMETALATION-PALLADIUM CATALYZED COUPLING WITH 2-AZA-PI-ALLYL PALLADIUM COMPLEXES

Authors
ODONNELL MJ LI M BENNETT WD GROTE T
Citation
Mj. Odonnell et al., SYNTHESIS OF BETA,GAMMA-UNSATURATED AMINO-ACID DERIVATIVES BY ALKYNE CARBOMETALATION-PALLADIUM CATALYZED COUPLING WITH 2-AZA-PI-ALLYL PALLADIUM COMPLEXES, Tetrahedron letters, 35(50), 1994, pp. 9383-9386
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
50
Year of publication
1994
Pages
9383 - 9386
Database
ISI
SICI code
0040-4039(1994)35:50<9383:SOBADB>2.0.ZU;2-D
Abstract
Zirconium-catalyzed carboalumination of terminal or symmetrical intern al alkynes followed by palladium-catalyzed coupling of the resulting v inylalane with Schiff base acetate 1 gives protected beta, gamma-unsat urated amino acid derivatives (vinylglycines) 6.