REGIOSELECTIVE BOND-CLEAVAGE OF VINYLCYCLOPROPANE DERIVATIVES WITH THE ZIRCONOCENE-BUTENE COMPLEX

Authors
HANZAWA Y HARADA S NISHIO R TAGUCHI T
Citation
Y. Hanzawa et al., REGIOSELECTIVE BOND-CLEAVAGE OF VINYLCYCLOPROPANE DERIVATIVES WITH THE ZIRCONOCENE-BUTENE COMPLEX, Tetrahedron letters, 35(50), 1994, pp. 9421-9424
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
50
Year of publication
1994
Pages
9421 - 9424
Database
ISI
SICI code
0040-4039(1994)35:50<9421:RBOVDW>2.0.ZU;2-7
Abstract
The regioselective bond cleavage of vinylcyclopropanes with zirconocen e-butene complex gave eta(3)-and/or eta(1)-allylic zirconocene derivat ives depending on the substitutional pattern of the cyclopropyl ring. The reactions and characterization of the complexes were carried out.