AL2O3 SUPPORTED KF - AN EFFICIENT MEDIATOR IN THE EPOXIDATION OF ELECTRON-DEFICIENT ALKENES WITH T-BUOOH

Authors
YADAV VK KAPOOR KK
Citation
Vk. Yadav et Kk. Kapoor, AL2O3 SUPPORTED KF - AN EFFICIENT MEDIATOR IN THE EPOXIDATION OF ELECTRON-DEFICIENT ALKENES WITH T-BUOOH, Tetrahedron letters, 35(50), 1994, pp. 9481-9484
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
50
Year of publication
1994
Pages
9481 - 9484
Database
ISI
SICI code
0040-4039(1994)35:50<9481:ASK-AE>2.0.ZU;2-1
Abstract
KF-AL(2)O(3) is discovered to promote epoxidation of electron deficien t alkenes. Functional groups that are labile to aqueous basic conditio ns survive. The steric demand for the reaction is higher than that for alkaline H2O2.