K. Tominaga et al., PREPARATION OF CONDUCTIVE ZNO-AL FILMS BY A FACING TARGET SYSTEM WITHA STRONG MAGNETIC-FIELD, Thin solid films, 253(1-2), 1994, pp. 9-13
Transparent conductive ZnO:A1 films were prepared in Ar gas by a plana
r magnetron sputtering system with facing targets, where strong intern
al magnets were contained in target holders to confine the plasma betw
een the targets. A film resistivity of 4 x 10(-4) Ohm cm was attained
at a substrate temperature of 200 degrees C. However, the film resisti
vity increased with increasing substrate temperature, due to a decreas
e of the carrier concentration. The reason for this phenomenon was the
decrease of Zn donors in the film as native donors or an increase of
Zn defects. When excess Zn atoms were supplied during film growth, a l
ow resistivity of 2 x 10(-4) Ohm cm was obtained even at a substrate t
emperature of 250 degrees C.