Srp. Silva et Gaj. Amaratunga, USE OF SPACE-CHARGE-LIMITED CURRENT TO EVALUATE THE ELECTRONIC DENSITY-OF-STATES IN DIAMOND-LIKE CARBON THIN-FILMS, Thin solid films, 253(1-2), 1994, pp. 146-150
Diamond-like carbon thin films are characterized using the space-charg
e limited current (SCLC) under electron and hole injection. An electro
nic density of states diagram derived using SCLC shows similarities to
the Davies-Mott model, with localized states within the midgap region
and band tailing at the edges of the gap. The density of midgap state
s for diamond-like carbon is of the order of 10(18) cm(-3) eV(-1) and
increases to 10(21) cm(-3) eV(-1) at the localized states associated w
ith the pi-pi bands. Activation energy and SCLC analysis show a defec
t state density of the order of 10(19) cm(-3) eV(-1) close to the cent
re of the band gap.