A quartz microbalance technique was employed to measure characteristic
slip times for ethane and ethylene monolayers adsorbed on silver and
chemisorbed oxygen/silver surfaces. These systems have been suggested
as model systems for studies of the relative contributions of electron
ic and phonon processes towards frictional energy losses. Slip times f
or the chemisorbed oxygen/silver surfaces are observed to be longer th
an those for silver. Based on this observation, it is argued that elec
tronic contributions to friction should be considered whenever conduct
ing surfaces are involved. Potential connections between the atomic-sc
ale result and macroscopic observation are discussed.