NOVEL CHLOROTRIMETHYLSILANE CATALYZED STEREOSELECTIVE DECONJUGATION OF BETA-BROMO (OR IODO) SUBSTITUTED ALPHA,BETA-UNSATURATED ACYCLIC KETONE

Authors
LUO FT HSIEH LC
Citation
Ft. Luo et Lc. Hsieh, NOVEL CHLOROTRIMETHYLSILANE CATALYZED STEREOSELECTIVE DECONJUGATION OF BETA-BROMO (OR IODO) SUBSTITUTED ALPHA,BETA-UNSATURATED ACYCLIC KETONE, Tetrahedron letters, 35(51), 1994, pp. 9585-9588
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
51
Year of publication
1994
Pages
9585 - 9588
Database
ISI
SICI code
0040-4039(1994)35:51<9585:NCCSDO>2.0.ZU;2-R
Abstract
TMSCl catalyzed stereoselective isomerization (deconjugation) of beta- substituted alpha,beta-unsaturated ketones to the corresponding (Z)-be ta,gamma-unsaturated ketones and its mechanism studies are described.