2-(METHYLTHIO)PENTAFLUOROPROPENE

Authors
ANDREEV VG SIZOV AY KOLOMIETS AF
Citation
Vg. Andreev et al., 2-(METHYLTHIO)PENTAFLUOROPROPENE, Russian chemical bulletin, 43(1), 1994, pp. 75-79
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
1
Year of publication
1994
Pages
75 - 79
Database
ISI
SICI code
1066-5285(1994)43:1<75:2>2.0.ZU;2-A
Abstract
2-(Methylthio) pentafluoropropene was obtained by dehydrofluorination of methyl 2H-hexafluoroisopropyl sulfide by the BF3.NEt(3) complex. It s reactivity with respect to allyl alcohol and hexamethyldisilazane wa s studied. The electrophilcity of 2-(methylthio)pentafluoropropene was compared with the properties of terminal polyfluoroalkenes whose beha vior in these reactions has been studied previously.