PHOTOCHEMICAL ADDITION OF DIETHYL-ETHER TO ,BETA,BETA',BETA'-TETRAKIS(TRIFLUOROMETHYL)DIVINYL ETHER

Authors
VOLKONSKY AY POLISHCHUK VR KAGRAMANOVA EM MYSOV EI MYSOVA NE ANTIPIN MY STRUCHKOV YT
Citation
Ay. Volkonsky et al., PHOTOCHEMICAL ADDITION OF DIETHYL-ETHER TO ,BETA,BETA',BETA'-TETRAKIS(TRIFLUOROMETHYL)DIVINYL ETHER, Russian chemical bulletin, 43(1), 1994, pp. 80-83
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
43
Issue
1
Year of publication
1994
Pages
80 - 83
Database
ISI
SICI code
1066-5285(1994)43:1<80:PAODT,>2.0.ZU;2-V
Abstract
The 1:1 adducts of diethyl and ,beta,beta',beta'-tetrakis(trifluoromet hyl)divinyl ether (1), i.e., -(trifluoromethyl)enthyl]-2-6-dimethyl-1, 4-dioxane (2) (3 isomers) and fluoromethyl-3-[3,3,3-trifluoro-2(triflu oromethyl) propenyloxy]pentane (3), have been obtained by UV-irradiati on of a solution of divinyl ether 1 in diethyl ether. The X-ray struct ural investigation of the all-(e)-isomer of dioxane (2) has been carri ed out.