H. Zillgen et al., STRUCTURAL AND MAGNETIC-PROPERTIES OF ULTRATHIN FE FILMS DEPOSITED ATLOW-TEMPERATURE ON CU(100), Surface science, 321(1-2), 1994, pp. 32-46
Recently iron films have been grown on Cu(100) mainly using two differ
ent procedures. Iron was either deposited at room temperature or at lo
w temperature (around 100 K). Surprisingly enough, the magnetic proper
ties of films showed a pronounced dependence upon the growth temperatu
re. Therefore we have investigated magnetism, structure and morphology
of iron films grown at 100 K. The measurements show a strong dependen
ce of the magnetic properties on the film structure. Below 4.6 ML, Fe
grows in the ferromagnetic fee phase. The film structure is characteri
zed by enlarged interlayer spacings and a reconstruction pattern, whic
h is indicative for an instability towards shear displacements in the
[011] direction. Upon increasing thickness the perpendicular magnetiza
tion switches in-plane around 4.6 ML. The reorientation is correlated
with a structural transition to bcc iron. This phase grows in four dif
ferent domains with Pitsch orientation, i.e. the bcc (110) plane paral
lel to the Cu(100) substrate. The phase transition to bcc iron differs
considerably from the martensitic mechanism effective for room-temper
ature growth. Possibly a local shear displacement enables a direct tra
nsition from ferromagnetic fee iron to the bcc phase. In contrast to f
ilms deposited at 300 K, no antiferromagnetic fee phase is stabilized.
This has a pronounced influence on the thickness dependence of the co
ercivity.