J. Hartmann et al., CHEMICAL SENSING WITH CAVITANDS - INFLUENCE OF CAVITY SHAPE AND DIMENSIONS ON THE DETECTION OF SOLVENT VAPORS, Sensors and actuators. B, Chemical, 35(1-3), 1996, pp. 154-157
The influence of structural parameters of the receptors on the respons
e of cavitand coated quartz-crystal-microbalance (QCM) sensors to seve
ral organic vapors is reported. Enhanced selectivity toward specific a
nalytes is obtained through CH-pi interactions, while sensitivity can
be improved by introducing long alkyl chains on cavitands to generate
highly dispersed layers. Application of cavitand coated QCM sensors fo
r the detection of organic analytes in water is also reported.