STRUCTURAL CHARACTERIZATION OF BIPHENYL ESTER-BASED LC MOLECULES - PECULIARITIES OF CYCLIC SILOXANE-BASED MATERIALS

The X-ray meridional profiles of a series of liquid crystalline molecu les possessing the same mesogen but different siloxane-based backbones and spacer lengths are compared. Siloxane cores investigated include rings of different sizes, linear polysiloxanes, and short linear segme nts. The presence of diffuse, periodic reflections for ring-based comp ounds is attributed in part to translational association of the mesoge nic units along the director (strings). The absence of these reflectio ns in smaller, more flexible cores indicates that the localization of strong scattering units induced by the cyclic and linear cores also co ntributes to the strength of this molecular association. Correlations between measured correlation lengths, orientation parameters, and ''st ring'' lengths are discussed in detail. Preliminary molecular modeling is used to investigate the origins of these peculiar scattering pheno mena as a function of the molecular architecture.