CRYSTAL-STRUCTURE OF PT(S2COET)2

Authors
ROGERS RD ANDROWSKI MJ BOND AH
Citation
Rd. Rogers et al., CRYSTAL-STRUCTURE OF PT(S2COET)2, Journal of chemical crystallography, 24(10), 1994, pp. 707-710
Citations number
22
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
24
Issue
10
Year of publication
1994
Pages
707 - 710
Database
ISI
SICI code
1074-1542(1994)24:10<707:COP>2.0.ZU;2-4
Abstract
The crystals of Pt(S2COEt)2 are orthohombic, Pbca, with (at 20-degrees -C) a = 7.799(3), b = 7.368(6), c = 20.588(7) angstrom, D(calc) = 2.46 g cm-3 for Z = 4. The platinum atom residues on a crystallographic ce nter of inversion and is bound to the four sulfur atoms of the xanthat o ligand in a square planar geometry. The Pt-S distances are 2.313(6) and 2.320(7) angstrom with an intraligand S-Pt-S angle of 75.1(2)-degr ees.