Immobilization of volative organic compounds (VOCs) in contaminated so
ils by solidification/stabilization (S/S) processes is an attractive p
otential remediation process. The objectives of this study were as fol
lows: to evaluate S/S procedures, including a new process with a VOC a
bsorbent and silica coatings; to apply a straightforward and inexpensi
ve analytical technique for characterizing VOC behavior during process
ing; and to propose the expanded use of waste materials such as contam
inated soil, rice hulls, and shredded-tire particles. We investigated
how the adsorbents, absorbents and encapsulating agents can be combine
d to retard volatilization and resist acidic aqueous leaching of tolue
ne. The toluene released at each step of the S/S process was determine
d by an accurate headspace analysis method. Results showed that combin
ing shredded-tire particles for absorption and sodium silicate for enc
apsulation is a promising method for immobilization of toluene in soil
.