V. Costantino et al., AXICERAMIDE-A AND AXICERAMIDE-B, 2 NOVEL TRI-A-GLYCOSYLCERAMIDES FROMTHE MARINE SPONGE AXINELLA SP, Liebigs Annalen der Chemie, (12), 1994, pp. 1181-1185
Two new glycosphingolipids, axiceramide A (1a) and B (2a), have been i
solated as their peracetates (1b and 2b, respectively) from the marine
sponge Axinella sp., and their structures elucidated by spectroscopic
and chemical analysis. Axiceramide A and B, both composed of a comple
x mixture of homologues, are the first example of natural triglycosylc
eramides with three hexopyranose units all engaged in alpha-glycosidic
linkages.