F. Sorensen et Hjs. Petersen, FORMULATION AND RECYCLING OF WATER-BASED DEGREASING AGENTS - EFFECTS ON OCCUPATIONAL-HEALTH AND ENVIRONMENTAL-PROTECTION, Hazardous waste & hazardous materials, 11(3), 1994, pp. 361-370
In metal degreasing, aqueous alkaline solutions can often be substitut
ed for organic solvents. Such water-based degreasing agents should be
formulated so that associated negative impacts on occupational health
and the environment are minimized. With these goals in mind, a review
and an evaluation of chemicals utilization in water-based degreasing a
gents has been carried out. These include strongly alkaline agents, so
dium metasilicate, complexing agents, corrosion inhibitors, surfactant
s, organic solvents, bactericides, coloring agents, and perfumes. In a
shop test a water-based degreasing agent formulated in accordance wit
h these criteria has been shown to be able to degrease aluminum parts
contaminated with oils from a draw process to an acceptable duality of
cleanness before burnishing. By recycling the degreasing agent in a m
icrofiltration unit it was possible to increase the service life of th
e bath 5 times, and to reduce the use of chemicals such as the builder
component to 20%, the surfactant component to 30%, and water utilizat
ion for setting up baths to 20%. Further, process down time has been d
ecreased for emptying and setting up baths thereby also reducing the a
ttendant occupational health and safety risks. There is a need for fur
ther tests of other degreasing agents formulated with the same criteri
a for additional metals and metal parts with different contamination a
nd cleanliness standards. New developments in microfiltration units sh
ould also be exploited.