DESIGNATED MOLECULAR DECONSTRUCTION - THE FACILE TRANSFORMATION OF GA(N(SIME3)2)(OSIME3)2PY (PY = PYRIDINE) TO GAN

Authors
BARRY ST RICHESON DS
Citation
St. Barry et Ds. Richeson, DESIGNATED MOLECULAR DECONSTRUCTION - THE FACILE TRANSFORMATION OF GA(N(SIME3)2)(OSIME3)2PY (PY = PYRIDINE) TO GAN, Chemistry of materials, 6(12), 1994, pp. 2220-2221
Citations number
17
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Chemistry of materials → ACNP
ISSN journal
08974756
Volume
6
Issue
12
Year of publication
1994
Pages
2220 - 2221
Database
ISI
SICI code
0897-4756(1994)6:12<2220:DMD-TF>2.0.ZU;2-1
Abstract
The new complex Ga(N(SiMe3)2)(OSiMe3)2py undergoes a smooth thermolysi s, as monitored by H-1 NMR and GC/MS, at 155-degrees-C to yield to gra y powder, (Me3Si)2O, and free pyridine. The X-ray diffraction powder p attern of the gray powder evolves into that of hexagonal GaN upon heat ing. A related complex, [Li(THF)2][Ga(N(SiMe3)2)(OSiMe3)2Cl], is repor ted and characterized by single-crystal X-ray diffraction.