SYNTHESIS AND STRUCTURE OF ZN(H2PO4)(2)(HPO4)CENTER-DOT-H2N2C6H12

Authors
PATARIN J MARLER B HUVE L
Citation
J. Patarin et al., SYNTHESIS AND STRUCTURE OF ZN(H2PO4)(2)(HPO4)CENTER-DOT-H2N2C6H12, European journal of solid state and inorganic chemistry, 31(10), 1994, pp. 909-920
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
31
Issue
10
Year of publication
1994
Pages
909 - 920
Database
ISI
SICI code
0992-4361(1994)31:10<909:SASOZ>2.0.ZU;2-8
Abstract
A new zincophosphate Zn(H2PO4)(2)HPO4.H2N2CgH12 was obtained at room t emperature form a ZnO/P2O5/R/H2O mixture, R being the dabconium cation . The crystal structure was determined by single crystal X-ray diffrac tion. The symmetry is orthorhombic a = 0.9777(2) nm, b = 1.0640(2) nm, c = 1.5384(3) nm, space group P2(1)2(1)2(1). The structure consists o f parallel (Zn(H2PO4)2-O-P(OOH)-O-) chains loosely interconnected thro ugh the dabconium cations.