TETRAKIS(TRIMETHYLPHENYLAMMONIUM) OCTA-MU-BROMO-DIBROMOHEXACUPRATE(I)

Authors
HU GZ HOLT EM
Citation
Gz. Hu et Em. Holt, TETRAKIS(TRIMETHYLPHENYLAMMONIUM) OCTA-MU-BROMO-DIBROMOHEXACUPRATE(I), Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1890-1892
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
50
Year of publication
1994
Part
12
Pages
1890 - 1892
Database
ISI
SICI code
0108-2701(1994)50:<1890:TO>2.0.ZU;2-4
Abstract
The title complex, [N(CH3)(3)(C6H5)](4)[Cu6Br10], contains a centrosym metric eight-membered ring of alternating Cu and Br atoms fused to two six-membered rings of alternating Cu and Br atoms. The average Cu-Br bond length is 2.377(4) Angstrom. A terminal Br atom is attached to on e Cu atom of each of the six-membered rings [Cu-Br 2.290 (4) Angstrom] . Two close Cu...Cu contacts [2.664(4) and 2.706(4) Angstrom] exist in each six-membered ring.